Zhibin Yu

In recent years, remarkable optoelectronic properties have been discovered in a group of halide perovskite semiconductors. Their potential to invigorate the current solar cell and light-emitting diode (LED) industries has been demonstrated by achieving very high device efficiencies in relatively short periods. While higher efficiency records are pursued, an equally important task is to improve their device reliability. So far, most reported perovskite solar cells and LEDs employed a polycrystalline thin film for light absorbing or light emitting purposes. The size of the grains in such films typically varied from sub-100 nanometers to a few micrometers. The high density of grain boundary defects can trap charge carriers and aid the diffusion of water molecules and ionic species in the perovskites, deteriorating their structural integrity and transportation properties in long-term applications.

We recently have invented a new process enabling the formation of perovskite thin films with a ultra-large and uniform grain size. The large grain size will significantly reduce the density of grain boundaries, and the films perform nearly the same as single crystalline materials. In addition, the simple solution process in our approach will potentially more practical to scaled up for future high throughput industrial production. The new discovery is based on our scientific understanding to precisely control the nucleation sites and nucleation densities of halide perovskites during film formation on a substrate.

Our halide perovskite thin films with large and uniform grains can exhibit enhanced structural and morphological stability in ambient air. For instance, efficient LEDs had been made with our methylammonium lead tribromide films after exposing them in air for three months without encapsulation. Our halide perovskite thin films also showed greatly reduced ionic migration tendency under an external electrical field. Photo-detectors had been fabricated using our methylammonium lead triiodide films. The devices exhibited 10 times lower dark current at a constant applied voltage compared to devices with conventional halide perovskite thin films that were processed using previously reported methods. In addition, no measurement hysteresis was observed in our halide perovskite thin films when a dynamic voltage was applied at both dark and illuminated conditions.

An FSU researcher created a novel material comprised of halide perovskite crystals embedded in a polymer matrix for radiation blocking and detection. The material is lightweight and lead free. Other materials require expensive and long manufacturing processes, but this novel material can be manufactured in a variety of ways such as solution-based drop casting, hot pressing, melt extrusion, injection molding, and 3D printing, to save time and money. Electrodes can be embedded in the material for passive and accurate x-ray and gamma-ray detection.  

Third party independent testing has shown that the material is 50% more effective than current state of the art radiation blocking technology. These semiconducting nanocrystals are uniformly dispersed in the polymer matrix to not only block radiation but also detect high energy radiation.